Published Open Access
In ferroelectrics, manifestation of a strong electromechanical coupling is attributed to both engineered domain morphology and phase transformations. However, realization of large sustainable and reversible strains and polarization rotation has been limited by fatigue, nonlinearity and hysteresis losses. Here, we demonstrate that large strain and polarization rotation can be generated for over 40 × 106 cycles with little fatigue by realization of a reversible ferroelectric-ferroelectric phase transition in  cut Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 (PIN-PMN-PT) relaxor ferroelectric single crystal. Direct tuning of this effect through combination of stress and applied electric field, confirmed both macroscopically and microscopically with x-ray and Raman scattering, reveals the local symmetry while sweeping through the transition with a low applied electric field (
Finkel, P.; Staruch, M.; Amin, A.; Ahart, M.; and Lofland, Samuel E., "Simultaneous Stress and Field Control of Sustainable Switching of Ferroelectric Phases" (2015). Faculty Scholarship for the College of Science & Mathematics. 56.
Finkel, P., Staruch, M., Amin, A., Ahart, M., & Lofland, S. (2015). Simultaneous stress and field control of sustainable switching of ferroelectric phases. Scientific Reports, 5(1), 13770.