Date Approved
6-17-2021
Embargo Period
6-17-2021
Document Type
Dissertation
Degree Name
Ph.D. Doctor of Philosophy in Materials Science and Engineering
Department
Physics and Astronomy
College
College of Science & Mathematics
Sponsor
Johnson Matthey Inc.
Advisor
Jeffrey Hettinger, Ph.D.
Committee Member 1
Wei Xue, Ph.D.
Committee Member 2
Lei Yu, Ph.D.
Committee Member 3
Samuel Lofland, Ph.D.
Keywords
Electrochemistry, Electrode Coatings, Neurostimulation electrode, Platinum Group Metal Oxides, Reactive Magnetron Sputtering, Thin Film
Subject(s)
Metallic oxides; Coatings
Disciplines
Materials Science and Engineering
Abstract
In this dissertation, thin film single, binary, and ternary metal oxides of iridium (Ir), ruthenium (Ru), rhodium (Rh), and palladium (Pd) were synthesized for use as electrode/microelectrode coatings for neural interfacing applications using DC reactive magnetron sputtering. Synthesis conditions which enhanced the electrochemical properties of films as measured by cyclic voltammetry and electrochemical impedance spectroscopy in a phosphate buffered saline solution of the single metal oxides were identified to be 30 mTorr working pressure, 20% oxygen partial pressure, and cathode power densities ≤ 4.9 W/cm2. These parameters were then used to develop the binary and ternary metal oxide films.
The binary metal oxides studied included Ir(1-x)Mx where M = Pd, Rh, Ru, and the ternary metal oxides studied included Ir(1-x-z)MxMz’, where M,M´ = Pd, Rh, and Ru. The binary metal oxide concentrations which produce robust microstructures and exceptional electrochemical performance have been identified to be x ≥ 0.5 for Ir(1-x)RhxOy, x ≥ 0.34 for Ir(1-x)RuxOy, and x ≥ 0.14 for Ir(1-x)PdxOy. Similar compositional ranges have been identified for the ternary metal oxides and include x ≥ 0.16 and z ≥ 0.05 for Ir(1-x-z)PdxRuzOy, x ≥ 0.13 and z ≥ 0.04 for Ir(1-x-z)PdxRhzOy, and x ≥ 0.2 and z ≥ 0.14 for Ir(1-x-z)RuxRhzOy.
Recommended Citation
Taylor, Gregory Vincent, "Investigation of single, binary, and ternary metal oxides of iridium, rhodium, and palladium for neural interfacing applications" (2021). Theses and Dissertations. 2918.
https://rdw.rowan.edu/etd/2918